How to charge the lithium iron phosphate*LiFePO4 battery correctly?
The full name of LiFePO4 is lithium iron phosphate lithium ion battery.Because its performance is particularly suitable for power applications, the word "power" is added in the name, namely, lithium iron phosphate power battery.Some people call it a "lithium iron power battery," and do you know how to charge lithium iron phosphate?The following for you to introduce the lithium iron phosphate battery charging skills.
1, Before solve the problem, first we need to understand the structure and working principle of lithium iron phosphate batteries. LiFePO4 as the positive pole of the battery, connected to the battery positive electrode by aluminum foil and polymer is among the diaphragm, which separates the positive and negative, but cannot pass lithium ionic and electronic, right is composed of carbon (graphite) battery cathode, the copper foil and negative connection of the battery. Between the upper and lower end of the battery is the battery electrolyte, the battery by metal enclosure sealed package.When the lithium iron phosphate battery is charged, the lithium ions in the positive electrode migrate to the negative electrode through the polymer membrane.During discharge, lithium ions in the negative electrode migrate through the diaphragm towards the positive electrode.Lithium-ion batteries are named for the way lithium ions move back and forth between charge and discharge.
2. During battery charging, lithium ions migrate from the surface of lithium iron phosphate crystal to the crystal surface. Under the action of electric field force, lithium ions enter the electrolyte, pass through the diaphragm, and then migrate to the surface of graphite crystal through the electrolyte, and then embed into the graphite lattice.At the same time, the electrons flow to the positive aluminum foil collector through the conductive body, and then flow to the negative copper foil collecting fluid through the polar ear, battery pole column, external circuit, negative pole column and negative ear, after that flow to the graphite negative pole through the conductive body, so that the charge of the negative pole reaches the balance.When lithium ion is deintercalated from lithium iron phosphate, it is converted into iron phosphate.
3. When the battery is discharged, lithium ions are removed and inlaid from the graphite crystal, enter the electrolyte, pass through the diaphragm, and then migrate to the surface of lithium iron phosphate crystal through the electrolyte, and then re-embedded into the crystal lattice of lithium iron phosphate through the surface.At the same time, the battery flows to the negative copper foil collector through the conductive body, then flows to the positive aluminum foil collector through the pole ear, the negative pole column of the battery, the external circuit, the positive pole column and the positive pole ear of the battery, after that flows to the positive pole of lithium iron phosphate through the conductive body, so as to balance the charge of the positive pole.
Note:
Please pay attention to water proof and dust proof when using lithium iron phosphate battery, so there should be no water in the storage place, which will affect the performance and service life of the battery.
Correct charging method for lithium iron phosphate battery pack
The charging method of CCCV is recommended for LiFePO4 battery pack, that is, constant current first and then constant voltage.Constant current recommendation is 0.3Cc.Constant voltage is recommended to be 3.65. That is, the battery should be charged with 0.3C current during constant current process. When the battery voltage reaches 3.65V, the battery should be charged with 3.65V constant voltage.When you use the balance power supply to charge, also pay attention to see the charging current, it is recommended not to use too high voltage charge, adjust the voltage, ensure the charging current in 0.5C below, that`s good for the battery.
General upper limit of the lithium iron phosphate battery voltage 3.7 ~ 4 V, discharge threshold voltage of 2 ~ 2.5 V, comprehensive consideration of discharge capacity, discharge voltage, charging time, constant current capacity percentage, security, the five aspects, using constant current constant voltage charging scheme, for the lithium iron phosphate battery pack, charge a reasonable limit set the voltage from 3.55 V to 3.70 V, the recommended value of 3.60 ~ 3.65 V, discharge threshold voltage of 2.2 V to 2.5 V.
The charger of lithium iron phosphate battery is different from ordinary lithium battery.The maximum termination voltage of lithium batteries is 4.2 volts;The lithium iron phosphate battery pack is 3.65 volts.When charging a lithium iron phosphate battery pack, it is the line connected by the balanced charging plate. Generally, it is charged in series from both ends. The voltage of the charger is greater than that of the battery pack.The voltage of each single cell detected by the line is equivalent to that of parallel regulator tubes. The charging voltage of each single cell will not exceed the regulator value, while other single cells will continue to be charged through the regulator tube bypass charging.
Since the charge of each cell is close to full at this time, it is just balancing each cell, so the charging current is low, and the charge of each cell is replenishing and balancing.The charger can only protect the terminal voltage of the entire battery pack. The balanced charging plate ensures that each unit is overcharged and each unit is fully charged. The charging of the entire lithium battery pack cannot be stopped due to the charging of one battery cell.
2020 06/03